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Carbon
fibre is the reinforcement material of choice for "advanced"
composites, particularly following significant price reductions
over the past decade. A major advantage of carbon fibres is
their higher fatigue resistance compared to glass
or Aramid. Unlike these last two materials,
carbon fibres do not suffer from stress rupture. Carbon fibres
are supplied in tows and may vary from 1000 fibres per tow
to hundreds of thousands of fibres per tow.
Untreated
carbon fibres do not wet easily, so adhesion to the matrix
must be achieved by good mechanical interference coupled with
surface treatment of the fibre which allows chemical bonding
between the fibre and the matrix. Careful fabrication is required,
however, to produce good materials as strong bonds cannot
be achieved.
Some
polymer composites for electrical purposes such as shielding
do not require significant structural strength. The attractive
property for such materials is the high conductivity of carbon
fibre. Most carbon fibres are derived from polyacrylonitrile,
but for even higher conductivity, fibres derived from pitch
can have three times the conductivity of copper.
At
room temperature the coefficient of thermal expansion of carbon
fibres along their axes is slightly negative. Above about
700C the coefficient becomes positive.
Carbon
fibre properties depend on the structure of the carbon used.
Typically they come defined as standard, intermediate and
high modulus fibres. Indicative materials properties are:
| |
Standard
modulus |
Intermediate
modulus |
High
modulus |
| Tensile
Strength |
3450-4830
MPa |
3450-6200
MPa |
3450-5520
MPa |
| Young's
Modulus |
220-241
GPa |
290-297
GPa |
345-448
GPa |
| Elongation
at break |
1.5-2.2%
|
1.3-2.0%
|
0.7-1.0% |
Ref
ASM Vol 21 Handbook.
|